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Journal of the Korean Society for Environmental Analysis 2013;16(2):71-76.
Study on the Sampling Bag Stability for the Substances Requiring Preparation for Accidents -Focusing on Acrolein and Propylene Oxide-
가스상 사고대비물질 시료채취 백 보존성 연구 -아크롤레인과 산화프로필렌을 중심으로-
이진선1, 김기준1, 윤준헌1, 최경희1, 조석연2
1국립환경과학원 화학물질연구과
2인하대학교
Abstract
To help a safer control of toxic chemicals, this study was conducted to investigate the storage stability of acrolein (ACR) and propylene oxide (PO), both of which are highly inflammable and volatile in Tedlar bags for gaseous chemical sampling. Their storage stability was analyzed considering storage temperatures (2 and 25), chemical concentrations (low conc. ppm and high conc. ppm) and storage times (0, 48, 96, and 144 hr). The bags were also divided into two groups and compared against each other for stability: one group contained a single type of chemical and the other included a mixture of chemicals. As a result, the two chemicals were found to have a low storage stability based on chemical reactivity and storage time. While PO showed statistical significance in terms of concentration and mixing type, ACR presented statistical significance in temperature in the bag with a single type of chemical substance.
Key Words: Tedlar bag, Storage stability, GC/MS, Substances requiring preparation for accidents, Acrolein,Propylene oxide
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